Tuesday, 8 November 2005
10

Influence of Selected Soil Properties on the Kinetics of Soil Acid-Base Buffer Reactions.

Mark Rékási1, Imre Czinkota2, Mária Csubák3, and Peter Czanik2. (1) Research Institute for Soil Science and Agricultural Chemistry, Hermann Otto 15., Budapest, Hungary, (2) Szent Istvan University, Páter K. 1., Gödöllő, Hungary, (3) University of Debrecen, Egyetem tér 1., Debrecen, Hungary

Our work discusses the background of soil acid-base buffer reactions. We investigated the kinetics of acid and base neutralisation - the rate of proton transfer reactions – that alters with the soil properties and characteristics of soil colloids. To describe the kinetics of buffer reactions we applied pH-stat titrations. 25 acidic soil samples were used from different regions of Hungary. Titration at a given pH level (pH8.2 and pH3) was achieved with an equipment and software combination built for this purpose. The measurements were carried out in a 1:40 soil / 1 M KCl solution suspension. For the titration 0.1 M HCl and 0.1 M NaOH solutions were used. To evaluate results the time and added base or acid quantities are extrapolated to infinite time using a function fitted on these data. The duration of measurement was 8 hours. The applied function is the following:

y = C + a1 • (1 - e-k1t)+ a2 • (1 - e-k2t)

Where: C — amount of base or acid to reach the given pH, cmol/kg

y — amount of fed base or acid, cmol/kg

t — time, sec

a1 — base or acid consumption of faster process, cmol/kg

a2 — base or acid consumption of slower process, cmol/kg

k1 — rate constant of faster process, s-1

k2 — rate constant of slower process, s-1

Our aim was to find and describe the relations among parameters of this function and selected properties of soils: pH, clay+silt content, organic matter, hydrolytic acidity, CEC and exchangeable cations. To reveal the connection of these properties with kinetics of acid-base buffer reactions we used stepwise linear regression analysis an correlation analysis.


Handout (.pdf format, 61.0 kb)

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