Friday, 14 July 2006
89-9

Reducing Cadmium Phytoextractability by Coal Bottom Ash.

Chang Oh Hong, Pil Joo Kim, Hong Hee Chang, and Chan Yu. Division of applied Life Science, Gyeongsang University, 900 Kaswa-Dong, Chinju, 660-701, South Korea

Coal bottom ash is generally considered to be a ferro-aluminosilicate mineral and has a higher pH. In acidic and Cd contaminated soil, the coal bottom ash can be a good amendment for increasing Cd immobilization and for decreasing Cd uptake of crop plants. In addition compost having very high indigenous negativity can contribute on increasing Cd holding capacity of soil and then on decreasing Cd uptake of plant. The objectives of this study are to evaluate the effect of coal bottom ash on cadmium(Cd) phytoextractbility in a gold mine tailing affected soil. Bottom ash was applied at 4 levels of 0, 20, 40, 80 Mg ha-1 and compost at 2 levels of 0 and 30 Mg ha-1. A radish cultivar (Raphanus sativa L.) was sown by hand in the experimental field on August 27, 2005 and harvested on October 29, 2005. Radish yield was increased slightly with increasing application of bottom ash. It was maximized at level of BA 40 Mg ha-1. Radish yield was more effectively increased by compost addition. Cd uptake by radish was significantly reduced with increasing application of bottom ash. Addition of bottom ash and compost more significantly decreased exchangeable Cd concentration than addition of bottom ash. The water soluble + exchangeable Cd fraction was significantly decreased with increasing application of bottom ash, but residual fraction was increased. Soil pH and negativity were highly increased by addition of bottom ash. Reducing Cd phytoavailability can be attributed primarily to immobilization of Cd by enhanced pH-induced increases in negative charge. Conclusively, bottom ash could be good amendment to reduce Cd phytoavailability and extractability in Cd contaminated arable soil.

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