2008 Joint Annual Meeting (5-9 Oct. 2008): Speciation of Copper in Soils.

741-6 Speciation of Copper in Soils.



Wednesday, 8 October 2008: 10:00 AM
George R. Brown Convention Center, 360C
Daniel Strawn, University of Idaho, Soil and Land Resources, University of Idaho, PO Box 442339 Ag Sci. 242, Moscow, ID 83844-2339 and Leslie Baker, University of Idaho, PO Box 442339, Dept. of Plant Soil And Entomological Sciences, Moscow, ID 83844-2339
Copper is commonly present in soils as a contaminant.  The mobility and bioavailability of the Cu is a function of the speciation.  In this project we investigate Cu speciation in 6 soils using advanced bulk and micro-spectroscopic techniques.  X-ray absorption spectroscopy of 5 different soils showed that the majority of the Cu is complexed to soil organic matter (SOM).  Elemental distributions showed no correlations of Cu with metals, suggesting that Cu has a preferential association for SOM functional groups.  In this presentation we will discuss the properties of Cu and the associated SOM based on the interpretation of the molecular structures observed and soil properties.